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Trace determination of transition metals with preconcentration (MiPCT), post-column reaction, and UV/VIS detection

AN-U-067

ja

The determination of transition metals by ion chromatography is possible with direct conductivity detection (see AN-C-137) as well as with UV/VIS detection after post-column reaction. Here, the cations are separated as anionic complexes and analyzed after post-column reaction with PAR with subsequent UV/VIS detection. Speciation determination of iron (separation of Fe(II) and Fe(III)) is possible with this procedure. For trace analysis, Metrohm Inline Preconcentration Technique (MiPCT) is applied.

The determination of transition metals by ion chromatography is possible with direct conductivity detection (see AN-C-137) as well as with UV/VIS detection after post-column reaction. Here, the cations are separated as anionic complexes and analyzed after post-column reaction with PAR with subsequent UV/VIS detection. Speciation determination of iron (separation of Fe(II) and Fe(III)) is possible with this procedure. For trace analysis, Metrohm Inline Preconcentration Technique (MiPCT) is applied.

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