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石油馏分中的溴数

AN-T-187

2020-10

zh

Ecological determination according to ASTM D1159 with toluene as solvent

溴数表示不饱和程度，是通过在烯烃双键上简单地添加溴来表示的。物质中每存在一摩尔碳碳双键（C=C），就会消耗一摩尔溴。在石油产品中，溴数与烯烃含量相对应。在本应用说明中，它们被甲苯取代。这使得测定更加生态化。滴定在 OMNIS 系统上结合双铂丝电极自动进行。通过这种设置，可以实现快速、准确的电位滴定测定。

The bromine number indicates the degree of unsaturation and relies on the simple addition of bromine to the double bond of alkenes. One mole of bromine is consumed for each mole of carbon-carbon double (C=C) bond present in a substance. In petroleum products, the bromine number corresponds to the olefin content.

Normally, chlorinated solvents are used for the determination of the bromine number. In this Application Note they have been replaced by toluene. This makes the determination more ecological. The titration is performed automatically on an OMNIS system in combination with a double Pt-wire electrode. With this setup, a fast and accurate determination by potentiometric titration can be realized.

The analysis is demonstrated on petroleum distillate.

According to the expected bromine number, an appropriate amount of sample is dissolved in toluene.

Figure 1. OMNIS system consisting of an OMNIS Advanced Titrator and an OMNIS Dosing Module equipped with a double Pt-wire electrode for indication.

The analysis is carried out on an OMNIS system consisting of an OMNIS Advanced Titrator, an OMNIS Dosing Module, and a double Pt-wire electrode.

Sample and titration solvent (consisting of toluene, methanol, sulfuric acid, and glacial acetic acid) are pipetted into a thermostated vessel. While stirring, the solution is cooled to between 0–5 °C. After reaching this temperature, the solution is titrated with standardized bromine until after the equivalence point is reached.

Steep and smooth curves are achieved with this setup. The results are very reproducible with relative standard deviations < 0.2 %.

With the presented analysis, a bromine number of 10.80 g bromine/100 g petroleum distillate (n = 5; SD(rel) = 0.19%) is obtained.

Figure 2. Titration curve of the determination of the bromine number of a petroleum distillate sample.

After reaching the temperature of 0–5 °C, the titration is automatically started. There is therefore no further need to observe the temperature. The titration curves are steep and easy to evaluate. Due to this point, the reproducibility is very good and the criteria of ASTM D1159 regarding reproducibility is fulfilled.

Additionally, the exchange of chlorinated solvents by toluene leads to a more environmentally friendly application with a comparable precision.

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Internal reference: AW TI CH1 1245-122017