饮用水镍钴双金属铋滴电极检测系统

AN-V-223

2020-05

Simultaneous determination in the ng/L range on the Bi drop electrode

镍污染的主要来源是电镀、冶金作业或从管道和配件中浸出。石油和化工行业的催化剂是钴的主要应用领域。在这两种情况下，金属要么直接排放，要么通过废水-河流途径进入饮用水系统。因此，欧盟立法规定饮用水中的镍浓度限值为 20 µg/L。无毒铋滴电极的独特性能与 AdSV 相结合，使其在灵敏度方面表现非常好。

The main sources of nickel pollution are electroplating, metallurgical operations, or leaching from pipes and fittings. Catalysts for the petroleum and chemical industries are major application fields for cobalt. In both cases, the metal is either released directly, or via the waste water-river pathway into the drinking water system. Therefore in the EU the legislation specifies 20 µg/L as the limit value for the Ni concentration in drinking water.

The simultaneous and straightforward determination of nickel and cobalt is based on adsorptive stripping voltammetry (AdSV). The unique properties of the non-toxic Bi drop electrode combined with AdSV results in an excellent performance in terms of sensitivity. The limit of detection for 30 s deposition time is approximately 0.2 µg/L for nickel and 0.1 µg/L for cobalt, and can be lowered further by increasing the deposition time. This method is best suited for automated systems or process analyzers, allowing fully automatic determination in large sample series.

Drinking water, mineral water, sea water

The water sample is pipetted into the measuring vessel. Ammonia / ammonium chloride buffer and the complexing agent dimethylglyoxime (DMG) are added, and the simultaneous determination of nickel and cobalt is carried out with a 884 Professional VA using the parameters specified in Table 1. The concentration is determined by two additions of a nickel and cobalt standard addition solution.

The Bi drop electrode is electrochemically activated prior to the first determination.

Figure 1. 884 Professional VA fully automated for VA analysis

**Table 1.** Parameters
Parameter	Setting
Mode	SQW – Square wave
Deposition potential	-0.8 V
Deposition time	30 s
Start potential	-0.8 V
End potential	-1.3 V
Peak potential Ni	-0.97 V
Peak potential Co	-1.12 V

Working electrode: Bi drop
Reference electrode: Ag/AgCl/KCl (3 mol/L)
Auxiliary electrode: Glassy carbon rod

The method is suitable for the determination of nickel and cobalt concentrations in water samples from β(Ni²⁺) = 0.2–8 µg/L and β(Co²⁺) = 0.1–10 µg/L.

Figure 2. Determination of nickel and cobalt in tap water spiked with β(Ni) = 0.5 µg/L and β(Co) = 0.5 µg/L

**Table 2.** Result
Sample	Ni (μg/L)	Co (μg/L)
Tap water spiked with β(Ni) = 0.5 µg/L and β(Co) = 0.5 µg/L	0.58	0.54

Application Bulletin 440: Determination of nickel and cobalt in water samples by adsorptive stripping voltammetry with a Bi drop electrode

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饮用水镍钴双金属铋滴电极检测系统

AN-V-223

瑞士万通中国

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